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We study the optical properties of spacetime around a novel black hole in general relativity coupled to nonlinear electrodynamics, which is asymptotically flat. First, we study the angular velocity and Lyapunov exponent in unstable photon circular orbits in the novel spherically symmetric black hole spacetime. Later, we obtain the rotating black hole solution using the Newman-Janis algorithm and determine the event horizon properties of the black hole. We analyze the effective potential for the circular motion of photons in the spacetime of the novel rotating black hole. Also, we analyze the photon sphere around the novel black hole and its shadow using celestial coordinates. We obtain that an increase of the black hole spin and charge as well as nonlinear electrodynamics field nonlinearity parameters causes an increase in the distortion parameter of the black hole shadow, while, the area of the shadow and its oblateness decrease. Moreover, we also obtain the constraint values for the black hole charge and the nonlinearity parameters using Event Horizon Telescope data from shadow sizes of supermassive black holes Sgr A* and M87*. Finally, the emission rate of black hole evaporation through Hawking radiation is also studied.